Newsportal - Ruhr-Universität Bochum
Catalytic activity of individual cobalt oxide nanoparticles determined
Precious metal-free nanoparticles could serve as powerful catalysts in the future, for example for hydrogen production. To optimize them, researchers must be able to analyze the properties of individual particles. A new method for this has been suggested by a team from the Center for Electrochemistry at Ruhr-Universität Bochum (RUB) and the Institute of Inorganic Chemistry at the University of Duisburg-Essen (UDE). The group developed a method using a robotic arm that allows them to select individual particles under an electron microscope and place them on a nanoelectrode for electrochemical analysis. The method is described in the journal Angewandte Chemie, published online in advance 19 November 2020.
Using a robotic arm to deposit nanoparticles onto electrode
For the studies, the scientists used hexagon-shaped particles of cobalt oxide with diameters of 180 to 300 nanometers, which the Duisburg-Essen team consisting of Professor Stephan Schulz and Sascha Saddeler had synthesized. In the experiment, the particles catalyzed the so-called oxygen evolution reaction. During the electrolysis of water, hydrogen and oxygen are formed, with the limiting step in this process currently being the partial reaction in which the oxygen is formed. More efficient catalysts for the oxygen evolution reaction would simplify the efficiency for electrochemical water splitting under formation of hydrogen. Nanoparticle catalysts are supposed to help with this. Since their catalytic activity often depends on their size or shape, it is important to understand the properties of individual particles in order to find the optimal catalysts.
The Bochum team consisting of Thomas Quast, Dr. Harshitha Barike Aiyappa, Dr. Patrick Wilde, Dr. Yen-Ting Chen and Professor Wolfgang Schuhmann analyzed selected cobalt oxide particles first microscopically, then electrochemically. “Using a movable robotic arm, we can pick out individual nanoparticles under the electron microscope,” Schuhmann explains. “The selected particle, which we then already know microscopically, we place on a tiny electrode to test what it can do as a catalyst.” The researchers then use electrochemical methods to measure its catalytic activity for the oxygen evolution reaction.
High catalytic activity
In this way, the chemists analyzed several individual particles. Since they knew the size and crystal orientation of a particle, they were able to relate the catalytic activity to the number of cobalt atoms. “Here, the particles showed remarkably high activities in the oxygen evolution reaction, and the measured current densities exceeded commercially available alkaline electrolyzers by more than 20 times,” says Stephan Schulz.
“We believe that by applying the proposed methodology, single particle analysis of catalyst materials has finally reached the point of reliable and comparatively simple sample preparation and characterization, which are crucial for establishing structure-function relationships,” the authors write in conclusion.
Since 2007, the three Ruhr region universities have been engaged in close strategic cooperation under the umbrella of the University Alliance Ruhr (UA Ruhr). By pooling their strengths, the partner institutions are systematically expanding their output. There are now over 100 cooperations in the fields of research, teaching and administration, all built on the principle of being “better together”. With over 120,000 students and almost 1,300 professors, the UA Ruhr is one of the largest and best-performing hubs for science and technology in Germany.
The work was funded by the German Research Foundation within the Collaborative Research Center/Transregio “Heterogeneous Oxidation Catalysis in the Liquid Phase” (TRR 247) and the Cluster of Excellence Ruhr Explores Solvation, short Resolv (EXC 2033-390677874), by the European Research Council in the Horizon 2020 Research and Innovation Program (CasCat, 833408) as well as by the Alexander von Humboldt Foundation and the Chemical Industry Fund.
Thomas Quast, Harshitha Barike Aiyappa, Sascha Saddeler, Patrick Wilde, Yen-Ting Chen, Stephan Schulz, Wolfgang Schuhmann: Single entity electrocatalysis of individual ‘picked‐and‐dropped’ Co3O4 nanoparticles on the tip of a carbon nanoelectrode, in: Angewandte Chemie International Edition, 2020, DOI: 10.1002/anie.202014384
Prof. Dr. Wolfgang Schuhmann
Center for Electrochemistry
Faculty of Chemistry and Biochemistry
Tel.: +49 234 32 26200
Prof. Dr. Stephan Schulz
Center for Nanointegration Duisburg-Essen
Faculty of Chemistry
University of Duisburg-Essen
Phone: +49 201 18 34635
15 December 2020